| Polyoxometalate-loaded Nanocellulose Sponge as a Novel Catalyst for the Regioselective Hydroboration of Phenylacetylene |
| Click here to download the full text |
| Citation of this paper: |
| Hits: 1344 |
| Download times: 1291 |
| Author Name | Affiliation | | GuoQing Yang1 | 1. Key Lab of Science and Technology of Eco-textile, Ministry of Education, College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai, 201620, China | | CongCong Zhang1 | 1. Key Lab of Science and Technology of Eco-textile, Ministry of Education, College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai, 201620, China | | BiJia Wang1,2,* | 1. Key Lab of Science and Technology of Eco-textile, Ministry of Education, College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai, 201620, China
2. Innovation Center for Textile Science and Technology of DHU, Donghua University, Shanghai, 201620, China | | ZhiPing Mao1,2 | 1. Key Lab of Science and Technology of Eco-textile, Ministry of Education, College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai, 201620, China
2. Innovation Center for Textile Science and Technology of DHU, Donghua University, Shanghai, 201620, China | | Hong Xu1,2 | 1. Key Lab of Science and Technology of Eco-textile, Ministry of Education, College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai, 201620, China
2. Innovation Center for Textile Science and Technology of DHU, Donghua University, Shanghai, 201620, China | | Yi Zhong1,2 | 1. Key Lab of Science and Technology of Eco-textile, Ministry of Education, College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai, 201620, China
2. Innovation Center for Textile Science and Technology of DHU, Donghua University, Shanghai, 201620, China | | XueLing Feng1,2 | 1. Key Lab of Science and Technology of Eco-textile, Ministry of Education, College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai, 201620, China
2. Innovation Center for Textile Science and Technology of DHU, Donghua University, Shanghai, 201620, China | | XiaoFeng Sui1,2,* | 1. Key Lab of Science and Technology of Eco-textile, Ministry of Education, College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai, 201620, China
2. Innovation Center for Textile Science and Technology of DHU, Donghua University, Shanghai, 201620, China |
|
| Fund Project:This work was financially supported by the Fundamental Research Funds for the Central Universities (No. 2232018A3-04, No. 2232018-02, and No. 2232018G-043) and the Program of Introducing Talents of Discipline to Universities (No. 105-07-005735). |
| |
| Abstract:In this work, an amino-modified cellulose nanofiber sponge was prepared and used as a support for polyoxometalate (POM) catalysts with a high loading efficiency. Fourier transform infrared spectroscopy, thermogravimetric analysis, and energy-dispersive X-ray spectroscopy revealed that an Anderson-type POM, (NH4)4[CuMo6O18(OH)6]·5H2O was successfully immobilized on the sponge based on electrostatic interactions. Morphological analysis indicated that the POM-loaded sponge retained its porous structure and that the POM was homogeneously distributed on the sponge walls. The POM-loaded sponge exhibited excellent mechanical properties by recovering 79.9% of its original thickness following a 60% compression strain. The POM-loaded sponge was found to effectively catalyze the hydroboration of phenylacetylenes, yielding excellent conversion and regioselectivity of up to 96% and 99%, respectively. Its catalytic activity remained unchanged after five reuse cycles. These findings represent a scalable strategy for immobilizing POMs on porous supports. |
| keywords:cellulose nanofiber polyoxometalates catalyst immobilization hydroboration heterogeneous catalyst |
| HTML View Full Text View/Add Comment Download reader |
|
|
|