| Solvatochromic Probe Based on Nano-cellulose Membrane Coated with Zn-ter-pyridine Complex in a Layer-by-Layer Manner |
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| Author Name | Affiliation | | XinPing Li1, 2 | 1. Shaanxi Provincial Key Laboratory of Papermaking Technology and Specialty Paper Development, College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science and Technology, Xi'an, Shaanxi Province, 710021, China
2. State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou, Guangdong Province, 510640, China | | FaFa Song1 | 1. Shaanxi Provincial Key Laboratory of Papermaking Technology and Specialty Paper Development, College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science and Technology, Xi'an, Shaanxi Province, 710021, China | | Meng Zhang1 | 1. Shaanxi Provincial Key Laboratory of Papermaking Technology and Specialty Paper Development, College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science and Technology, Xi'an, Shaanxi Province, 710021, China | | BaiLiang Xue1 | 1. Shaanxi Provincial Key Laboratory of Papermaking Technology and Specialty Paper Development, College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science and Technology, Xi'an, Shaanxi Province, 710021, China | | JingYi Nie1 | 1. Shaanxi Provincial Key Laboratory of Papermaking Technology and Specialty Paper Development, College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science and Technology, Xi'an, Shaanxi Province, 710021, China | | ShunTian Jia1 | 1. Shaanxi Provincial Key Laboratory of Papermaking Technology and Specialty Paper Development, College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science and Technology, Xi'an, Shaanxi Province, 710021, China | | YaoYu Wang3 | 3. Northwest University, Xi'an, Shaanxi Province, 710069, China | | Zhao Zhang1, 2, 3,* | 1. Shaanxi Provincial Key Laboratory of Papermaking Technology and Specialty Paper Development, College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science and Technology, Xi'an, Shaanxi Province, 710021, China
2. State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou, Guangdong Province, 510640, China
3. Northwest University, Xi'an, Shaanxi Province, 710069, China |
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| Fund Project:This work was supported by National Natural Science Foundation of China (21703131, 31370578), Doctoral Scientific Research Foundation of Shaanxi University of Science and Technology (2016BJ-40), State Key Laboratory of Pulp and Paper Engineering (201821), China Postdoctoral Science Foundation (2018M643707), and Natural Science Foundation of Shaanxi Provincial Department of Education (18JK0122). |
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| Abstract:Solvatochromic materials have recently attracted increasing attention owing to their great significance in the security and sensor fields. In this study, ultrafast explicit and implicit information was collected regarding a fluorescent nanocellulose membrane produced from nanocellulose membranes coated with a Zn-terpyridine complex (Zn-tpy) in a layer-by-layer manner. The fluorescent emissions of the nanocellulose membrane changed from yellow (CIE: x=0.37, y=0.45) to green (CIE: x=0.32, y=0.47) under a dichloromethane environment and 365-nm irradiation. Due to the ease of dichloromethane volatilization, fluorescent emissions quickly returned to the original state. These solvatochromic nanocellulose membranes, with ultrafast explicit and implicit information, exhibited valuable application prospects in anti-counterfeiting techniques. |
| keywords:solvatochromic explicit and implicit Zn-terpyridine complex layer-by-layer nanocellulose membrane |
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